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In ancient Egypt, artists used an orange mineral pigment called realgar for tomb paintings, as well as other uses. It was also used later by Medieval artists for the colouring of manuscripts. Pigments were also made in ancient times from a mineral known as orpiment. Orpiment was an important item of trade in the Roman Empire and was used as a medicine in China although it contains arsenic and is highly toxic. It was also used as a fly poison and to poison arrows. Because of its yellow-orange colour, it was also a favourite with alchemists searching for a way to make gold, both in China and in the West. Before the late 15th century, the colour orange existed in Europe, but without the name; it was simply called yellow-red. Portuguese merchants brought the first orange trees to Europe from Asia in the late 15th and early 16th century, along with the Sanskrit naranga, which gradually became part of several European languages: "naranja" in Spanish, "laranja" in Portuguese, and "orange" in English.

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